Shuhe Han,⁺ Changhong Wang,⁺ Yuting Wang, Yifu Yu,* and Bin Zhang,* Electrosynthesis of Nitrate via the Oxidation of Nitrogen on Tensile Strained Palladium Porous Nanosheets, Angew. Chem. Int. Ed., 2021, 60, 4474-4478. DOI: 10.1002/anie.202014017

Abstract:

Nitrate is one of the essential raw ingredients in agriculture and industry. The electrochemical nitrogen oxidation reaction (NOR) is promising to replace the conventional nitrate synthesis industry with high energy consumption and greenhouse gas emission. Here, tensile-strained palladium porous nanosheets (Pd-s PNSs) were prepared. They exhibited enhanced activity for electrochemical NOR at ambient conditions, greatly outperforming Pd nanosheets.¹⁵N isotope labeling experiments proved that nitrate originated from nitrogen oxidation. Combining electrochemical in situ Raman and FTIR spectroscopy with density functional calculations, it was revealed that the tensile strain could facilitate the formation of NOR active species of PdO₂, leading to high activity.